Search results for "Cobalt nanoparticles"
showing 4 items of 4 documents
Magnetic properties of colloidal cobalt nanoclusters
2010
Abstract. Co nanoclusters were synthesized by an inverse-micelle chemical route. The magnetic and microstructural properties of the nanoparticles have been analyzed as a function of the surfactant (AOT and DEHP) and the drying method. Microstructural analysis has been performed by TEM and XANES; magnetic properties have been studied by hysteresis loops and zero-field cooling - field cooling (ZFC-FC) curves. TEM images show 2 to 4 nm sized particles spherical in shape. XANES measurements point out a significant presence of Co3O4 with metallic Co and some Co2+ bound to the surfactant. The presence of antiferromagnetic Co3O4 explains the magnetic transition observed at low T in both ZFC-FC mea…
Reversible Supracolloidal Self-Assembly of Cobalt Nanoparticles to Hollow Capsids and Their Superstructures
2017
| openaire: EC/FP7/291364/EU//MIMEFUN The synthesis and spontaneous, reversible supracolloidal hydrogen bond-driven self-assembly of cobalt nanoparticles (CoNPs) into hollow shell-like capsids and their directed assembly to higher order superstructures is presented. CoNPs and capsids form in one step upon mixing dicobalt octacarbonyl (Co2CO8) and p-aminobenzoic acid (pABA) in 1,2-dichlorobenzene using heating-up synthesis without additional catalysts or stabilizers. This leads to pABA capped CoNPs (core ca. 5nm) with a narrow size distribution. They spontaneously assemble into tunable spherical capsids (d≈50-200nm) with a few-layered shells, as driven by inter-nanoparticle hydrogen bonds th…
Superior Fischer-Tropsch performance of uniform cobalt nanoparticles deposited into mesoporous SiC
2020
Electrochemically-derived well-crystalline mesoporous silicon carbide (pSiC) was used as a host for cobalt nanoparticles to demonstrate superior catalytic performance during the CO hydrogenation according to Fischer-Tropsch. Colloidal Co nanoparticles (9 ± 0.4 nm) were prepared independently using colloidal recipes before incorporating them into pSiC and, for comparison purposes, into commercially available silica (Davisil) as well as foam-like MCF-17 supports. The Co/pSiC catalyst demonstrated the highest (per unit mass) catalytic activity of 117 µmol.g(CO)-1.g-1(Co).s-1 at 220 °C which was larger by about one order of magnitude as compared to both silica supported cobalt catalysts. Furthe…
(2010). Microstructure and magnetic properties of colloidal cobalt nano-clusters.
2010
The magnetic response of nanometer sized Co nanoparticles (NP) prepared using reverse micelle solutions are presented. The use of complementary structural and morphological probes (like transmission electron microscopy, high resolution electron microscopy, X-ray absorption spectroscopy) allowed to relate the magnetic properties to the size, morphology, composition and atomic structure of the nanoparticles. All data agree on the presence of a core–shell structure of NPs made of a metallic Co core surrounded by a thin Co-oxide layer. The core–shell microstructure of NPs affects its magnetic response mainly raising the anisotropy constant.